Selective oxidation of sp3 C-H bonds in water catalyzed by a glycinate-platinum(II) complex

George S. Chen; Jay A. Labinger; John E. Bercaw

doi:10.1021/om900267w

Selective oxidation of sp³ C-H bonds in water catalyzed by a glycinate-platinum(II) complex

George S. Chen, Jay A. Labinger, John E. Bercaw

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

In aqueous solution, [Pt^II(glycinato)Cl₂]^- catalyzes oxidation by [Pt^IVCl₆]^2- of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [Pt ^IICl_n(H₂O)_4-n]^2-n as the catalyst.

Original language	English (US)
Pages (from-to)	4899-4901
Number of pages	3
Journal	Organometallics
Volume	28
Issue number	17
DOIs	https://doi.org/10.1021/om900267w
State	Published - Sep 14 2009
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Selective oxidation of sp3 C-H bonds in water catalyzed by a glycinate-platinum(II) complex",

abstract = "In aqueous solution, [PtII(glycinato)Cl2]- catalyzes oxidation by [PtIVCl6]2- of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [Pt IICln(H2O)4-n]2-n as the catalyst.",

author = "Chen, {George S.} and Labinger, {Jay A.} and Bercaw, {John E.}",

year = "2009",

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journal = "Organometallics",

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T1 - Selective oxidation of sp3 C-H bonds in water catalyzed by a glycinate-platinum(II) complex

AU - Chen, George S.

AU - Labinger, Jay A.

AU - Bercaw, John E.

PY - 2009/9/14

Y1 - 2009/9/14

N2 - In aqueous solution, [PtII(glycinato)Cl2]- catalyzes oxidation by [PtIVCl6]2- of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [Pt IICln(H2O)4-n]2-n as the catalyst.

AB - In aqueous solution, [PtII(glycinato)Cl2]- catalyzes oxidation by [PtIVCl6]2- of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [Pt IICln(H2O)4-n]2-n as the catalyst.

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U2 - 10.1021/om900267w

DO - 10.1021/om900267w

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JF - Organometallics

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ER -

Selective oxidation of sp³ C-H bonds in water catalyzed by a glycinate-platinum(II) complex

Abstract

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