Origin of resonant Raman excitation profiles red-shifted from optical absorption profiles

J. M. Friedman; D. L. Rousseau; V. E. Bondybey

doi:10.1103/PhysRevLett.37.1610

Origin of resonant Raman excitation profiles red-shifted from optical absorption profiles

J. M. Friedman, D. L. Rousseau, V. E. Bondybey

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

We observe that the Raman excitation profile in matrix-isolated Br2 is significantly red-shifted from the absorption maximum and show that a straightforward relationship between the two can in general not be expected. A simple theory considering only the resonant contributions describes our data reasonably well. In addition, we discuss the effect on our results of interference between the B and Π1u1 states.

Original language	English (US)
Pages (from-to)	1610-1613
Number of pages	4
Journal	Physical Review Letters
Volume	37
Issue number	24
DOIs	https://doi.org/10.1103/PhysRevLett.37.1610
State	Published - 1976
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy

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10.1103/PhysRevLett.37.1610

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title = "Origin of resonant Raman excitation profiles red-shifted from optical absorption profiles",

abstract = "We observe that the Raman excitation profile in matrix-isolated Br2 is significantly red-shifted from the absorption maximum and show that a straightforward relationship between the two can in general not be expected. A simple theory considering only the resonant contributions describes our data reasonably well. In addition, we discuss the effect on our results of interference between the B and Π1u1 states.",

author = "Friedman, {J. M.} and Rousseau, {D. L.} and Bondybey, {V. E.}",

year = "1976",

doi = "10.1103/PhysRevLett.37.1610",

language = "English (US)",

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pages = "1610--1613",

journal = "Physical Review Letters",

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publisher = "American Physical Society",

number = "24",

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T1 - Origin of resonant Raman excitation profiles red-shifted from optical absorption profiles

AU - Friedman, J. M.

AU - Rousseau, D. L.

AU - Bondybey, V. E.

PY - 1976

Y1 - 1976

N2 - We observe that the Raman excitation profile in matrix-isolated Br2 is significantly red-shifted from the absorption maximum and show that a straightforward relationship between the two can in general not be expected. A simple theory considering only the resonant contributions describes our data reasonably well. In addition, we discuss the effect on our results of interference between the B and Π1u1 states.

AB - We observe that the Raman excitation profile in matrix-isolated Br2 is significantly red-shifted from the absorption maximum and show that a straightforward relationship between the two can in general not be expected. A simple theory considering only the resonant contributions describes our data reasonably well. In addition, we discuss the effect on our results of interference between the B and Π1u1 states.

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U2 - 10.1103/PhysRevLett.37.1610

DO - 10.1103/PhysRevLett.37.1610

M3 - Article

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JO - Physical Review Letters

JF - Physical Review Letters

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ER -

Origin of resonant Raman excitation profiles red-shifted from optical absorption profiles

Abstract

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