Molecular complexes of explosives with cyclodextrins. 2. Preparation and characterization of a solid complex of β-cyclodextrin with the nitramine 1,3,3-trinitroazetidine (TNAZ)

S. Cahill; A. G. Rinzler; F. J. Owens; S. Bulusu

doi:10.1021/j100079a033

Molecular complexes of explosives with cyclodextrins. 2. Preparation and characterization of a solid complex of β-cyclodextrin with the nitramine 1,3,3-trinitroazetidine (TNAZ)

S. Cahill, A. G. Rinzler, F. J. Owens, S. Bulusu

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A solid complex between 1,3,3-trinitroazetidine (TNAZ) and β-cyclodextrin has been isolated for the first time and characterized by the application of solution and solid-state NMR techniques, Raman spectroscopy, and differential scanning calorimetry experiments. All the techniques show clear differences in properties of the solid product from those of a simple physical mixture of the components, and when taken together, they provide convincing evidence for the complex formation.

Original language	English (US)
Pages (from-to)	7095-7100
Number of pages	6
Journal	Journal of physical chemistry
Volume	98
Issue number	28
DOIs	https://doi.org/10.1021/j100079a033
State	Published - 1994
Externally published	Yes

ASJC Scopus subject areas

General Engineering
Physical and Theoretical Chemistry

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year = "1994",

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AU - Rinzler, A. G.

AU - Owens, F. J.

AU - Bulusu, S.

PY - 1994

Y1 - 1994

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AB - A solid complex between 1,3,3-trinitroazetidine (TNAZ) and β-cyclodextrin has been isolated for the first time and characterized by the application of solution and solid-state NMR techniques, Raman spectroscopy, and differential scanning calorimetry experiments. All the techniques show clear differences in properties of the solid product from those of a simple physical mixture of the components, and when taken together, they provide convincing evidence for the complex formation.

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Molecular complexes of explosives with cyclodextrins. 2. Preparation and characterization of a solid complex of β-cyclodextrin with the nitramine 1,3,3-trinitroazetidine (TNAZ)

Abstract

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