[Me2Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Hyosun Lee; Jeffrey B. Bonanno; Tony Hascall; Joseph Cordaro; Juliet M. Hahn; Gerard Parkin

doi:10.1039/a900173e

[Me₂Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Hyosun Lee, Jeffrey B. Bonanno, Tony Hascall, Joseph Cordaro, Juliet M. Hahn, Gerard Parkin

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

A series of permethylated [Me₂Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me₂Si(C₅Me₄)]TiR₂ are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me₂Si(C₅Me₄)(C₅Me ₃CH₂)]TiR.

Original language	English (US)
Pages (from-to)	1365-1368
Number of pages	4
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/a900173e
State	Published - May 7 1999
Externally published	Yes

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[Me₂Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character. / Lee, Hyosun; Bonanno, Jeffrey B.; Hascall, Tony et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 9, 07.05.1999, p. 1365-1368.

Research output: Contribution to journal › Article › peer-review

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abstract = "A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.",

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AU - Cordaro, Joseph

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AU - Parkin, Gerard

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[Me₂Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Abstract

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