Mechanism for Fluorescence Quenching of Tryptophan by Oxamate and Pyruvate: Conjugation and Solvation-Induced Photoinduced Electron Transfer

Physics & Astronomy

• pyruvates 80%
• tryptophan 67%
• conjugation 60%
• solvation 55%
• carboxylates 52%
• electron transfer 51%
• amides 47%
• quenching 41%
• fluorescence 37%
• water 28%
• molecules 27%
• molecular orbitals 25%
• aqueous solutions 23%
• orbitals 17%
• hydrogen bonds 13%
• electrons 10%
• proteins 10%
• density functional theory 9%
• continuums 9%
• requirements 8%
• probes 7%
• ions 5%
• energy 3%

Engineering & Materials Science

• Fluorescence quenching 100%
• Solvation 81%
• Amides 57%
• Electrons 51%
• Molecules 49%
• Molecular orbitals 43%
• Carrier concentration 35%
• Fluorescence 29%
• Water 27%
• Quenching 26%
• Density functional theory 18%
• Hydrogen bonds 17%
• Ions 11%
• Proteins 11%

Chemical Compounds

• Oxamate 79%
• Pyruvate 53%
• Fluorescence Quenching 47%
• Tryptophan 47%
• Electron Transfer 35%
• Lowest Unoccupied Molecular Orbital 28%
• Amide 27%
• Electron Density 23%
• Molecule 17%
• Fluorescence 14%
• Frontier Orbital 13%
• Aqueous Solution 13%
• Protein Structure 12%
• Electron Acceptor 11%
• Solvation 10%
• Orbital 10%
• Density Functional Theory 7%
• Probe 7%
• Hydrogen Bond 7%
• Electron Particle 6%
• Energy 5%
• Ion 5%