Solvent-controlled Csp2→O silyl migration: The "one-pot" synthesis of 2,3-disubsituted thiophenes

Nelmi O. Devarie-Baez; Brian J. Shuhler; Hua Wang; Ming Xian

doi:10.1021/ol702149c

Solvent-controlled C^sp2→O silyl migration: The "one-pot" synthesis of 2,3-disubsituted thiophenes

Nelmi O. Devarie-Baez
, Brian J. Shuhler
, Hua Wang
, Ming Xian

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

(Chemical Equation Presented) An effective "one-pot" synthesis of disubstituted thiophene derivatives employing 3-bromo-2-silyl thiophenes has been developed. A solvent-controlled [1,4] C^sp2→O silyl migration was involved as the key step in this process.

Original language	English (US)
Pages (from-to)	4655-4658
Number of pages	4
Journal	Organic Letters
Volume	9
Issue number	22
DOIs	https://doi.org/10.1021/ol702149c
State	Published - Oct 25 2007
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol702149c

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AU - Shuhler, Brian J.

AU - Wang, Hua

AU - Xian, Ming

PY - 2007/10/25

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AB - (Chemical Equation Presented) An effective "one-pot" synthesis of disubstituted thiophene derivatives employing 3-bromo-2-silyl thiophenes has been developed. A solvent-controlled [1,4] Csp2→O silyl migration was involved as the key step in this process.

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Solvent-controlled C^sp2→O silyl migration: The "one-pot" synthesis of 2,3-disubsituted thiophenes

Abstract

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