Mechanism of dynamic nuclear polarization in high magnetic fields

C. T. Farrar; D. A. Hall; G. J. Gerfen; S. J. Inati; R. G. Griffin

doi:10.1063/1.1346640

Mechanism of dynamic nuclear polarization in high magnetic fields

C. T. Farrar, D. A. Hall, G. J. Gerfen, S. J. Inati, R. G. Griffin

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97 Scopus citations

Abstract

A model for analyzing polarization transfer via thermal mixing at high magnetic strengths has been developed. This model of electron cross-relaxation is used to study the field dependence of dynamic nuclear polarization and electron-electron double resonance. Polarization transfer proceeds via spin flip-flops between pairs of electronic spin packets whose Zeeman temperatures can differ from one another. The mechanism describes the spin dynamics of the 4-amino-TEMPO system.

Original language	English (US)
Pages (from-to)	4922-4933
Number of pages	12
Journal	Journal of Chemical Physics
Volume	114
Issue number	11
DOIs	https://doi.org/10.1063/1.1346640
State	Published - Mar 15 2001
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1346640

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abstract = "A model for analyzing polarization transfer via thermal mixing at high magnetic strengths has been developed. This model of electron cross-relaxation is used to study the field dependence of dynamic nuclear polarization and electron-electron double resonance. Polarization transfer proceeds via spin flip-flops between pairs of electronic spin packets whose Zeeman temperatures can differ from one another. The mechanism describes the spin dynamics of the 4-amino-TEMPO system.",

author = "Farrar, {C. T.} and Hall, {D. A.} and Gerfen, {G. J.} and Inati, {S. J.} and Griffin, {R. G.}",

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AU - Farrar, C. T.

AU - Hall, D. A.

AU - Gerfen, G. J.

AU - Inati, S. J.

AU - Griffin, R. G.

PY - 2001/3/15

Y1 - 2001/3/15

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AB - A model for analyzing polarization transfer via thermal mixing at high magnetic strengths has been developed. This model of electron cross-relaxation is used to study the field dependence of dynamic nuclear polarization and electron-electron double resonance. Polarization transfer proceeds via spin flip-flops between pairs of electronic spin packets whose Zeeman temperatures can differ from one another. The mechanism describes the spin dynamics of the 4-amino-TEMPO system.

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Mechanism of dynamic nuclear polarization in high magnetic fields

Abstract

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