Abstract
(Chemical Equation Presented) "Nitroso" knows: A process has been developed which converts unstable S-nitrosothiols into stable sulfenamide analogues (see scheme).Reductive ligation proceeds rapidly in mixed organic solvent/water systems to give high yields. By applying this reaction, an efficient strategy for detecting S-nitrosylation in proteins and other biological systems is envisioned.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 6598-6601 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 35 |
| DOIs | |
| State | Published - Aug 18 2008 |
| Externally published | Yes |
Keywords
- Nitrenes
- Nitrogen oxides
- Reductive ligation
- S-nitrosothiols
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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